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Literature DB >> 16623594

Gold(I)-catalyzed stereoselective formation of functionalized 2,5-dihydrofurans.

Andrea Buzas¹, Florin Istrate, Fabien Gagosz.

Abstract

[reaction: see text] A study concerning the gold(I)-catalyzed rearrangement of butynediol monobenzoates into functionalized 2,5-dihydrofurans is described. The mild reaction conditions employed allow the efficient and rapid stereoselective synthesis of a variety of 2,5-dihydrofurans via a sequence of two gold(I)-catalyzed isomerization steps.

Entities: Chemical

Year: 2006 PMID： 16623594 DOI： 10.1021/ol0606839

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

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