| Literature DB >> 16623561 |
Troy Lister1, Michael V Perkins.
Abstract
[reaction: see text] The protected precursor 30 to dolabriferol was generated by a DBU-induced, ester-forming, retro-Claisen process. The required linear carbon chain present in 22 was synthesized by a stereoselective lithium aldol reaction. The necessary aldehyde and ketone fragments were synthesized using stereocontrolled aldol reactions with the ethyl (S)-lactate derived ketone 13.Entities:
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Year: 2006 PMID： 16623561 DOI： 10.1021/ol060347s
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005