Literature DB >> 16620118

Fluorescent lifetime quenching near d = 1.5 nm gold nanoparticles: probing NSET validity.

T L Jennings1, M P Singh, G F Strouse.   

Abstract

The fluorescence behavior of molecular dyes at discrete distances from 1.5 nm diameter gold nanoparticles as a function of distance and energy is investigated. Photoluminescence and luminescence lifetime measurements both demonstrate quenching behavior consistent with 1/d(4) separation distance from dye to the surface of the nanoparticle. In agreement with the model of Persson and Lang, all experimental data show that energy transfer to the metal surface is the dominant quenching mechanism, and the radiative rate is unchanged throughout the experiment.

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Year:  2006        PMID: 16620118     DOI: 10.1021/ja0583665

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  34 in total

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