| Literature DB >> 16615170 |
Yun-kui Liu, Dan-qian Xu, Zhen-yuan Xu, Yong-min Zhang.
Abstract
A simple and convenient procedure for stereoselective synthesis of (Z)-allyl selenides has been developed by a one-pot reaction of diselenides with Baylis-Hillman adducts in the presence of samarium metal-trimethylsilyl chloride under mild conditions. Presumably, the diselenides are cleaved by Sm/TMSCl system to form selenide anions, which then undergo S(N)2' substitution of Baylis-Hillman adducts to produce the (Z)-allyl selenides.Entities:
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Year: 2006 PMID： 16615170 PMCID： PMC1462932 DOI： 10.1631/jzus.2006.B0393
Source DB: PubMed Journal: J Zhejiang Univ Sci B ISSN： 1673-1581 Impact factor: 3.066