Literature DB >> 16612805

Spontaneous absolute asymmetric synthesis in the presence of achiral silica gel in conjunction with asymmetric autocatalysis.

Tsuneomi Kawasaki1, Kenta Suzuki, Masako Shimizu, Keisuke Ishikawa, Kenso Soai.   

Abstract

An enantiomerically enriched pyrimidyl alkanol with either S or R configurations was obtained stochastically from the reaction between pyrimidine-5-carbaldehyde and diisopropylzinc in the presence of achiral silica gel in conjunction with asymmetric autocatalysis with amplification of chirality.

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Year:  2006        PMID： 16612805     DOI： 10.1002/chir.20273

Source DB:  PubMed          Journal:  Chirality        ISSN： 0899-0042            Impact factor:   2.437


  9 in total

1.  Parity-violation energy of biomolecules-IV: protein secondary structure.

Authors:  Francesco Faglioni; Inmaculada García Cuesta
Journal:  Orig Life Evol Biosph       Date:  2010-12-16       Impact factor: 1.950

2.  Stochastic and empirical models of the absolute asymmetric synthesis by the Soai-autocatalysis.

Authors:  Béla Barabás; Claudia Zucchi; Marco Maioli; Károly Micskei; Gyula Pályi
Journal:  J Mol Model       Date:  2015-02-03       Impact factor: 1.810

3.  Isotope chirality and asymmetric autocatalysis: a possible entry to biological chirality.

Authors:  Béla Barabás; Luciano Caglioti; Károly Micskei; Claudia Zucchi; Gyula Pályi
Journal:  Orig Life Evol Biosph       Date:  2008-06-03       Impact factor: 1.950

4.  On the biogenic origins of homochirality.

Authors:  Victor Sojo
Journal:  Orig Life Evol Biosph       Date:  2015-03-14       Impact factor: 1.950

Review 5.  Asymmetric Autocatalysis as an Efficient Link Between the Origin of Homochirality and Highly Enantioenriched Compounds.

Authors:  Kenso Soai; Tsuneomi Kawasaki; Arimasa Matsumoto
Journal:  Orig Life Evol Biosph       Date:  2022-08-12       Impact factor: 1.120

6.  Enantioselective C-C bond formation as a result of the oriented prochirality of an achiral aldehyde at the single-crystal face upon treatment with a dialkyl zinc vapor.

Authors:  Tsuneomi Kawasaki; Sayaka Kamimura; Ai Amihara; Kenta Suzuki; Kenso Soai
Journal:  Angew Chem Int Ed Engl       Date:  2011-06-15       Impact factor: 15.336

Review 7.  Asymmetric autocatalysis. Chiral symmetry breaking and the origins of homochirality of organic molecules.

Authors:  Kenso Soai
Journal:  Proc Jpn Acad Ser B Phys Biol Sci       Date:  2019       Impact factor: 3.493

8.  Computing the Parameter Values for the Emergence of Homochirality in Complex Networks.

Authors:  Andrés Montoya; Elkin Cruz; Jesús Ágreda
Journal:  Life (Basel)       Date:  2019-09-15

9.  Crystal Structure of the Isopropylzinc Alkoxide of Pyrimidyl Alkanol: Mechanistic Insights for Asymmetric Autocatalysis with Amplification of Enantiomeric Excess.

Authors:  Arimasa Matsumoto; Takaaki Abe; Atsushi Hara; Takayuki Tobita; Taisuke Sasagawa; Tsuneomi Kawasaki; Kenso Soai
Journal:  Angew Chem Int Ed Engl       Date:  2015-10-23       Impact factor: 15.336
  9 in total

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