Literature DB >> 16597129

Ultrafast study of the photochemistry of 2-azidonitrobenzene.

Ryan D McCulla1, Gotard Burdzinski, Matthew S Platz.   

Abstract

[reaction: see text] Ultrafast time-resolved studies of the photochemistry of 2-azidonitrobenzene demonstrate that the lifetimes of excited singlet 2-azidonitrobenzene and 2-nitrophenylnitrene are 500 fs and 8.3 ps, respectively, in solution at ambient temperature. The singlet nitrene is a discrete intermediate but is too short lived to undergo bimolecular reactions.

Entities:  

Year:  2006        PMID： 16597129     DOI： 10.1021/ol0602452

Source DB:  PubMed          Journal:  Org Lett        ISSN： 1523-7052            Impact factor:   6.005


  3 in total

1.  Photoaffinity labeling via nitrenium ion chemistry: protonation of the nitrene derived from 4-amino-3-nitrophenyl azide to afford reactive nitrenium ion pairs.

Authors:  Valentyna Voskresenska; R Marshall Wilson; Maxim Panov; Alexander N Tarnovsky; Jeanette A Krause; Shubham Vyas; Arthur H Winter; Christopher M Hadad
Journal:  J Am Chem Soc       Date:  2009-08-19       Impact factor: 15.419

2.  Non-blocking modulation contributes to sodium channel inhibition by a covalently attached photoreactive riluzole analog.

Authors:  Peter Lukacs; Mátyás C Földi; Luca Valánszki; Emilio Casanova; Beáta Biri-Kovács; László Nyitray; András Málnási-Csizmadia; Arpad Mike
Journal:  Sci Rep       Date:  2018-05-25       Impact factor: 4.379

3.  Synthesis of 2,1-benzisoxazole-3(1H)-ones by base-mediated photochemical N-O bond-forming cyclization of 2-azidobenzoic acids.

Authors:  Daria Yu Dzhons; Andrei V Budruev
Journal:  Beilstein J Org Chem       Date:  2016-05-04       Impact factor: 2.883
  3 in total

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