Literature DB >> 16594680

Metal-mediated efficient synthesis, structural characterization, and skeletal rearrangement of octasubstituted semibullvalenes.

Chao Wang1, Jian Yuan, Guotao Li, Zitao Wang, Shiwei Zhang, Zhenfeng Xi.   

Abstract

The first metal-mediated efficient synthesis of octasubstituted semibullvalenes, including octaalkyl and mixed tetraalkyl and tetraphenyl derivatives, was developed. The structures of these semibullvalenes were determined by single-crystal X-ray structural analysis. Their intramolecular skeletal rearrangement and reaction chemistry were investigated.

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Year:  2006        PMID: 16594680     DOI: 10.1021/ja0579208

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

1.  Zirconoarylation of alkynes through p-chloranil-promoted reductive elimination of arylzirconates.

Authors:  Xiaoyu Yan; Chao Chen; Chanjuan Xi
Journal:  Beilstein J Org Chem       Date:  2014-02-28       Impact factor: 2.883

  1 in total

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