Literature DB >> 16593632

Extension of the statistical theory of resonating valence bonds to hyperelectronic metals.

B Kamb1, L Pauling.   

Abstract

The statistical treatment of resonating covalent bonds in metals, previously applied to hypoelectronic metals, is extended to hyperelectronic metals and to metals with two kinds of bonds. The theory leads to half-integral values of the valence for hyperelectronic metallic elements.

Year:  1985        PMID: 16593632      PMCID: PMC390898          DOI: 10.1073/pnas.82.24.8284

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  1 in total

1.  A Theory of Ferromagnetism.

Authors:  L Pauling
Journal:  Proc Natl Acad Sci U S A       Date:  1953-06       Impact factor: 11.205

  1 in total
  5 in total

1.  A revised set of values of single-bond radii derived from the observed interatomic distances in metals by correction for bond number and resonance energy.

Authors:  L Pauling; B Kamb
Journal:  Proc Natl Acad Sci U S A       Date:  1986-06       Impact factor: 11.205

2.  Comparison of theoretical and experimental values of the number of metallic orbitals per atom in hypoelectronic and hyperelectronic metals.

Authors:  L Pauling; B Kamb
Journal:  Proc Natl Acad Sci U S A       Date:  1985-12       Impact factor: 11.205

3.  Crystal structure of hexagonal MnAl(4).

Authors:  L Pauling
Journal:  Proc Natl Acad Sci U S A       Date:  1987-06       Impact factor: 11.205

4.  Factors determining the average atomic volumes in intermetallic compounds.

Authors:  L Pauling
Journal:  Proc Natl Acad Sci U S A       Date:  1987-07       Impact factor: 11.205

5.  Principles determining the structure of high-pressure forms of metals: The structures of cesium(IV) and cesium(V).

Authors:  L Pauling
Journal:  Proc Natl Acad Sci U S A       Date:  1989-03       Impact factor: 11.205

  5 in total

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