| Literature DB >> 16592372 |
Abstract
The well-known formula for calculating the viscosity of hard sphere gases, eta(o) = 2(mkT)(1/2)/3pi(3/2)sigma(2), where sigma(2) is molecular cross section, is altered to eta(o) = K(MT)(1/2)/V(t) (2/3), where V(t) is the molal volume of a liquid that has expanded sufficiently to permit mean free paths long enough to have significant fractions of the random thermal momenta of molecules in free flight and M is molal mass.This formulation places upon a single straight line points for all nonpolar molecules, mono- and polyatomic molecules alike, over long ranges of temperature.Entities:
Year: 1976 PMID: 16592372 PMCID: PMC431439 DOI: 10.1073/pnas.73.12.4302
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205