| Literature DB >> 16591808 |
Abstract
Methane diffuses in water at 25 degrees C 3/5 as fast as it does in carbon tetrachloride. Since diffusivity depends mainly upon temperature, viscosity of the solvent, and molecular cross section of the diffusant, and since viscosities of H(2)O and CCl(4) at 25 degrees C are almost identical, one may infer that molecules of CH(4) in H(2)O are not imprisoned in "icebergs," and are retarded only by hydrogen bonds, not by encounters with "ice-like" aggregates.Entities:
Year: 1969 PMID: 16591808 PMCID: PMC223287 DOI: 10.1073/pnas.64.4.1329
Source DB: PubMed Journal: Proc Natl Acad Sci U S A ISSN: 0027-8424 Impact factor: 11.205