Literature DB >> 16578774

Intrinsic randomness and intrinsic irreversibility in classical dynamical systems.

M Courbage1, I Prigogine.   

Abstract

We continue our previous work on dynamic "intrinsically random" systems for which we can derive dissipative Markov processes through a one-to-one change of representation. For these systems, the unitary group of evolution can be transformed in this way into two distinct Markov processes leading to equilibrium for either t--> + infinity or t--> - infinity. To lift the degeneracy, we first formulate the second principle as a selection rule that is meaningful in intrinsically random systems. For these systems, this excludes a set of unrealizable states. As a result of this exclusion, permitted initial conditions correspond to a set of states that is not invariant through velocity inversion. In this way, the time-reversal symmetry of dynamics is broken and these systems acquire a new feature we may call "intrinsic irreversibility." The set of admitted initial conditions can be characterized by an entropy displaying the amount of information necessary for their preparation. The initial conditions selected by the second law correspond to a finite amount of information, while the initial conditions that are rejected correspond to an infinite amount of information and are therefore "impossible." We believe that our formulation permits a microscopic formulation of the second law of thermodynamics for well-defined classes of dynamical systems.

Entities:  

Year:  1983        PMID: 16578774      PMCID: PMC393832          DOI: 10.1073/pnas.80.8.2412

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  1 in total

1.  The second law as a selection principle: The microscopic theory of dissipative processes in quantum systems.

Authors:  I Prigogine; C George
Journal:  Proc Natl Acad Sci U S A       Date:  1983-07       Impact factor: 11.205

  1 in total

北京卡尤迪生物科技股份有限公司 © 2022-2023.