Literature DB >> 16578695

Some remarks about liquid metals.

D McLachlan1.   

Abstract

This paper proposes that the liquid state in metals consists of clusters, or globs, of ordered material separated by very thin layers of defects. The nature of the defects surrounding each glob and separating it from neighboring globs is the main feature of the theory. The volume of each defect and the energy to produce it is found to be only a fraction of that required to produce an ordinary vacancy in a solid. A close correlation is shown to exist between this theory and Eyring's theory of significant structures.(1-7) The heats of fusion and the volume changes on melting can be computed, as can be the coordination numbers in the liquid state.

Year:  1969        PMID: 16578695      PMCID: PMC277794          DOI: 10.1073/pnas.62.2.337

Source DB:  PubMed          Journal:  Proc Natl Acad Sci U S A        ISSN: 0027-8424            Impact factor:   11.205


  6 in total

1.  SIGNIFICANT STRUCTURES IN LIQUIDS. II.

Authors:  E J Fuller; T Ree; H Eyring
Journal:  Proc Natl Acad Sci U S A       Date:  1959-11       Impact factor: 11.205

2.  SIGNIFICANT STRUCTURES IN LIQUIDS, V. THERMODYNAMIC AND TRANSPORT PROPERTIES OF MOLTEN METALS.

Authors:  C M Carlson; H Eyring; T Ree
Journal:  Proc Natl Acad Sci U S A       Date:  1960-05       Impact factor: 11.205

3.  SIGNIFICANT STRUCTURES IN THE LIQUID STATE. I.

Authors:  H Eyring; T Ree; N Hirai
Journal:  Proc Natl Acad Sci U S A       Date:  1958-07-15       Impact factor: 11.205

4.  SIGNIFICANT STRUCTURES IN LIQUIDS, IV. LIQUID CHLORINE.

Authors:  T R Thomson; H Eyring; T Ree
Journal:  Proc Natl Acad Sci U S A       Date:  1960-03       Impact factor: 11.205

5.  SIGNIFICANT STRUCTURES IN LIQUIDS, III. PARTITION FUNCTION FOR FUSED SALTS.

Authors:  C M Carlson; H Eyring; T Ree
Journal:  Proc Natl Acad Sci U S A       Date:  1960-03       Impact factor: 11.205

6.  SIGNIFICANT LIQUID STRUCTURES, VI. THE VACANCY THEORY OF LIQUIDS.

Authors:  H Eyring; T Ree
Journal:  Proc Natl Acad Sci U S A       Date:  1961-04       Impact factor: 11.205

  6 in total

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