Literature DB >> 16568981

An S = 6 cyanide-bridged octanuclear FeIII4NiII4 complex that exhibits slow relaxation of the magnetization.

Dongfeng Li1, Sean Parkin, Guangbin Wang, Gordon T Yee, Rodolphe Clérac, Wolfgang Wernsdorfer, Stephen M Holmes.   

Abstract

The synthesis and structural and magnetic characterization of an S = 6 cyanide-bridged octanuclear FeIII4NiII4 (1) complex is described. Ac susceptibility and mu-SQUID measurements suggest that fast magnetization relaxation is present in zero-field due to quantum tunneling of the ground spin state (QTM) while application of small magnetic fields induces slow relaxation of the magnetization.

Entities:  

Year:  2006        PMID： 16568981     DOI： 10.1021/ja058626i

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  5 in total

1.  Covalent embedding of Ni2+/Fe3+ cyanometallate structures in silica by sol-gel processing.

Authors:  Elisabeth Felbermair; Andrey Sidorenko; Silke Paschen; Johanna Akbarzadeh; Herwig Peterlik; Ulrich Schubert
Journal:  Chemistry       Date:  2014-05-27       Impact factor: 5.236

2.  Trigonal antiprismatic Co(ii) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms.

Authors:  Yuan-Zhu Zhang; Silvia Gómez-Coca; Andrew J Brown; Mohamed R Saber; Xuan Zhang; Kim R Dunbar
Journal:  Chem Sci       Date:  2016-06-17       Impact factor: 9.825

3.  K⊂{[FeII(Tp)(CN)3]4[CoIII(pzTp)]3[CoII(pzTp)]}: a neutral soluble model complex of photomagnetic Prussian blue analogues.

Authors:  D Garnier; J-R Jiménez; Y Li; J von Bardeleben; Y Journaux; T Augenstein; E M B Moos; M T Gamer; F Breher; R Lescouëzec
Journal:  Chem Sci       Date:  2016-05-13       Impact factor: 9.825

4.  Easy axis anisotropy creating high contrast magnetic zones on magnetic tunnel junctions based molecular spintronics devices (MTJMSD).

Authors:  Bishnu R Dahal; Marzieh Savadkoohi; Andrew Grizzle; Christopher D'Angelo; Vincent Lamberti; Pawan Tyagi
Journal:  Sci Rep       Date:  2022-04-06       Impact factor: 4.379

5.  Spin state of a single-molecule magnet (SMM) creating long-range ordering on ferromagnetic layers of a magnetic tunnel junction - a Monte Carlo study.

Authors:  Andrew Grizzle; Christopher D'Angelo; José Martínez-Lillo; Pawan Tyagi
Journal:  RSC Adv       Date:  2021-09-30       Impact factor: 4.036
  5 in total

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