Literature DB >> 16551070

Magnetic transitions of single-component molecular metal [Au(tmdt)2] and its alloy systems.

Biao Zhou1, Mina Shimamura, Emiko Fujiwara, Akiko Kobayashi, Takeshi Higashi, Eiji Nishibori, Makoto Sakata, Hengbo Cui, Kazuyuki Takahashi, Hayao Kobayashi.   

Abstract

A single-component molecular conductor [Au(tmdt)2] (tmdt = trimethylenetetrathiafulvalenedithiolate) undergoes an antiferromagnetic phase transition at unprecedentedly high temperature (TN = 110 K). Black microcrystals of alloys, [Ni1-xAux(tmdt)2] (0.0 < x < 1.0) were prepared. The Au-rich system exhibited an antiferromagnetic transition. Metallic single crystal was obtained for x = 0.25.

Entities:  

Year:  2006        PMID: 16551070     DOI: 10.1021/ja0581144

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN: 0002-7863            Impact factor:   15.419


  1 in total

Review 1.  First-principles electronic-band calculations on organic conductors.

Authors:  Shoji Ishibashi
Journal:  Sci Technol Adv Mater       Date:  2009-07-06       Impact factor: 8.090

  1 in total

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