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Literature DB >> 16550268

Small molecule activation at uranium coordination complexes: control of reactivity via molecular architecture.

Ingrid Castro-Rodríguez¹, Karsten Meyer.

Abstract

Electron-rich uranium coordination complexes display a pronounced reactivity toward small molecules. In this Feature article, the exciting chemistry of trivalent uranium ions coordinated to classic Werner-type ligand environments is reviewed. Three fundamentally important reactions of the [(((R)ArO)3tacn)U]-system are presented that result in alkane coordination, CO/CO2 activation, and nitrogen atom-transfer chemistry.

Entities: Chemical

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Year: 2006 PMID： 16550268 DOI： 10.1039/b513755c

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

18 in total

1. Isolation and characterization of a uranium(VI)-nitride triple bond.

Authors: David M King; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal: Nat Chem Date: 2013-05-05 Impact factor: 24.427

2. Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

Authors: Benedict M Gardner; Gábor Balázs; Manfred Scheer; Ashley J Wooles; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal: Angew Chem Int Ed Engl Date: 2015-10-28 Impact factor: 15.336

3. Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

4. An Inverted-Sandwich Diuranium μ-η⁵:η⁵-Cyclo-P₅ Complex Supported by U-P₅ δ-Bonding.

Authors: Benedict M Gardner; Floriana Tuna; Eric J L McInnes; Jonathan McMaster; William Lewis; Alexander J Blake; Stephen T Liddle
Journal: Angew Chem Weinheim Bergstr Ger Date: 2015-04-27

5. Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings.

Authors: Ashley J Wooles; David P Mills; Floriana Tuna; Eric J L McInnes; Gareth T W Law; Adam J Fuller; Felipe Kremer; Mark Ridgway; William Lewis; Laura Gagliardi; Bess Vlaisavljevich; Stephen T Liddle
Journal: Nat Commun Date: 2018-05-29 Impact factor: 14.919

Small molecule activation at uranium coordination complexes: control of reactivity via molecular architecture.

1. Isolation and characterization of a uranium(VI)-nitride triple bond.

2. Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

3. Isolation of Elusive HAsAsH in a Crystalline Diuranium(IV) Complex.

4. An Inverted-Sandwich Diuranium μ-η⁵:η⁵-Cyclo-P₅ Complex Supported by U-P₅ δ-Bonding.

5. Uranium(III)-carbon multiple bonding supported by arene δ-bonding in mixed-valence hexauranium nanometre-scale rings.

6. An Inverted-Sandwich Diuranium μ-η(5):η(5)-Cyclo-P5 Complex Supported by U-P5 δ-Bonding.

7. [U(III) {N(SiMe2 tBu)2 }3 ]: a structurally authenticated trigonal planar actinide complex.

8. Synthesis and characterization of an f-block terminal parent imido [U═NH] complex: a masked uranium(IV) nitride.

9. Concomitant Carboxylate and Oxalate Formation From the Activation of CO₂ by a Thorium(III) Complex.

10. Evidence for single metal two electron oxidative addition and reductive elimination at uranium.