Literature DB >> 16538244

Mechanism of cellulose dissolution in the ionic liquid 1-n-butyl-3-methylimidazolium chloride: a 13C and 35/37Cl NMR relaxation study on model systems.

Richard C Remsing1, Richard P Swatloski, Robin D Rogers, Guillermo Moyna.   

Abstract

13C and 35/37Cl NMR relaxation measurements on several model systems demonstrate that the solvation of cellulose by the ionic liquid (IL) 1-n-butyl-3-methylimidazolium chloride ([C4mim]Cl) involves hydrogen-bonding between the carbohydrate hydroxyl protons and the IL chloride ions in a 1 ratio 1 stoichiometry.

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Year:  2006        PMID： 16538244     DOI： 10.1039/b600586c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  29 in total

1.  Glycoside hydrolase activities of thermophilic bacterial consortia adapted to switchgrass.

Authors:  John M Gladden; Martin Allgaier; Christopher S Miller; Terry C Hazen; Jean S VanderGheynst; Philip Hugenholtz; Blake A Simmons; Steven W Singer
Journal:  Appl Environ Microbiol       Date:  2011-07-01       Impact factor: 4.792

2.  Understanding the mechanism of cellulose dissolution in 1-butyl-3-methylimidazolium chloride ionic liquid via quantum chemistry calculations and molecular dynamics simulations.

Authors:  Hao Xu; Wenxiao Pan; Ruoxi Wang; Dongju Zhang; Chengbu Liu
Journal:  J Comput Aided Mol Des       Date:  2012-03-16       Impact factor: 3.686

3.  Designing tailored microbial and enzymatic response in ionic liquids for lignocellulosic biorefineries.

Authors:  Seema Singh
Journal:  Biophys Rev       Date:  2018-04-23

4.  Fermentable sugars by chemical hydrolysis of biomass.

Authors:  Joseph B Binder; Ronald T Raines
Journal:  Proc Natl Acad Sci U S A       Date:  2010-03-01       Impact factor: 11.205

5.  Bis-N-heterocyclic carbene palladium(IV) tetrachloride complexes: synthesis, reactivity, and mechanisms of direct chlorinations and oxidations of organic substrates.

Authors:  A Scott McCall; Hongwang Wang; John M Desper; Stefan Kraft
Journal:  J Am Chem Soc       Date:  2011-01-19       Impact factor: 15.419

6.  Protein Stabilization and Enzyme Activation in Ionic Liquids: Specific Ion Effects.

Authors:  Hua Zhao
Journal:  J Chem Technol Biotechnol       Date:  2015-11-19       Impact factor: 3.174

7.  Ionic liquid solutions as extractive solvents for value-added compounds from biomass.

Authors:  Helena Passos; Mara G Freire; João A P Coutinho
Journal:  Green Chem       Date:  2014-12       Impact factor: 10.182

8.  Bioprospecting metagenomics of decaying wood: mining for new glycoside hydrolases.

Authors:  Luen-Luen Li; Safiyh Taghavi; Sean M McCorkle; Yian-Biao Zhang; Michael G Blewitt; Roman Brunecky; William S Adney; Michael E Himmel; Phillip Brumm; Colleen Drinkwater; David A Mead; Susannah G Tringe; Daniel van der Lelie
Journal:  Biotechnol Biofuels       Date:  2011-08-04       Impact factor: 6.040

9.  Hydrogen bond basicity of ionic liquids and molar entropy of hydration of salts as major descriptors in the formation of aqueous biphasic systems.

Authors:  Helena Passos; Teresa B V Dinis; Ana Filipa M Cláudio; Mara G Freire; João A P Coutinho
Journal:  Phys Chem Chem Phys       Date:  2018-05-23       Impact factor: 3.676

10.  Elucidation of the effect of ionic liquid pretreatment on rice husk via structural analyses.

Authors:  Teck Nam Ang; Gek Cheng Ngoh; Adeline Seak May Chua; Min Gyu Lee
Journal:  Biotechnol Biofuels       Date:  2012-09-07       Impact factor: 6.040
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