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Literature DB >> 16536516

Mimicking [2,2]paracyclophane topology: molecular clips for the coordination-driven cofacial assembly of pi-conjugated systems.

Brigitte Nohra¹, Sébastien Graule, Christophe Lescop, Régis Réau.

Abstract

Self-assembly of CuI dimers, featuring a bridging phosphole ligand, and ditopic cyano-substituted chromophores affords nanosize supramolecular cationic rectangles. Due to the short Cu-Cu distance in the bimetallic clips, the coordinated chromophores are forced to participate in cofacial pi-pi interactions as evidenced by X-ray data. In addition, intermolecular pi-pi interactions in the solid state are observed leading to infinite columns of pi-stacked (para-phenylenevinylene)-based chromophores.

Entities: Chemical

Year: 2006 PMID： 16536516 DOI： 10.1021/ja058617+

Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419

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Cited

5 in total

5. Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C ₃-symmetric ligands.

Authors: Yuki Imai; Junpei Yuasa
Journal: Chem Sci Date: 2019-03-05 Impact factor: 9.825

5 in total

Mimicking [2,2]paracyclophane topology: molecular clips for the coordination-driven cofacial assembly of pi-conjugated systems.

1. Molecular solids: Co-crystals give light a tune-up.

2. Coordination Polymers based on the Neutral Ditopic Ligand (C₆H₄PO(OCH₃)₂)₂ Involving some f-Block Elements.

3. Phosphorus centers of different hybridization in phosphaalkene-substituted phospholes.

4. Positional isomers of cyanostilbene: two-component molecular assembly and multiple-stimuli responsive luminescence.

5. Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C ₃-symmetric ligands.

Mimicking [2,2]paracyclophane topology: molecular clips for the coordination-driven cofacial assembly of pi-conjugated systems.

1. Molecular solids: Co-crystals give light a tune-up.

2. Coordination Polymers based on the Neutral Ditopic Ligand (C6H4PO(OCH3)2)2 Involving some f-Block Elements.

3. Phosphorus centers of different hybridization in phosphaalkene-substituted phospholes.

4. Positional isomers of cyanostilbene: two-component molecular assembly and multiple-stimuli responsive luminescence.

5. Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C 3-symmetric ligands.

2. Coordination Polymers based on the Neutral Ditopic Ligand (C₆H₄PO(OCH₃)₂)₂ Involving some f-Block Elements.

5. Supramolecular chirality transformation driven by monodentate ligand binding to a coordinatively unsaturated self-assembly based on C ₃-symmetric ligands.