Literature DB >> 16518483

Diels-Alder reaction of acenes with singlet and triplet oxygen -- theoretical study of two-state reactivity.

A Ravikumar Reddy1, Michael Bendikov.   

Abstract

An interesting change in mechanism (from concerted to biradical) is described for the reaction of acenes (benzene through pentacene) with molecular oxygen (either singlet oxygen, 1Deltag-O2, or triplet oxygen, 3Sigmag-O2).

Entities:  

Year:  2006        PMID： 16518483     DOI： 10.1039/b513597d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

Review 1.  Strategies for the Synthesis of Higher Acenes.

Authors:  Ruth Dorel; Antonio M Echavarren
Journal:  European J Org Chem       Date:  2016-11-16

2.  Persistent Ambipolar Heptacenes and Their Redox Species.

Authors:  Nico Zeitter; Nikolai Hippchen; Steffen Maier; Frank Rominger; Andreas Dreuw; Jan Freudenberg; Uwe H F Bunz
Journal:  Angew Chem Int Ed Engl       Date:  2022-05-05       Impact factor: 16.823

3.  Effect of Twisting on the Capture and Release of Singlet Oxygen by Tethered Twisted Acenes.

Authors:  Anjan Bedi; Amit Manor Armon; Ori Gidron
Journal:  Org Lett       Date:  2020-09-23       Impact factor: 6.005

4.  Mechanism for the photodegradation of 9,10-dibutoxyanthracene in the presence of air.

Authors:  Ryotaro Seto; Arisa Sato; Keita Iuchi; Shunichi Himori; Hiroaki Gotoh
Journal:  PLoS One       Date:  2022-03-11       Impact factor: 3.240
  4 in total

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