Literature DB >> 16514462

Variation in crystallization conditions allows the isolation of trimeric as well as dimeric and monomeric forms of [(alkyl isocyanide)4RhI]+.

Ngon T Tran1, Jay R Stork, David Pham, Marilyn M Olmstead, James C Fettinger, Alan L Balch.   

Abstract

Trimeric green [(i-PrNC)12Rh(I)3]Cl3.4.5H2O, monomeric [(C6H11NC)4Rh(I)](BPh4) and [(i-PrNC)4Rh(I)](BPh4) (both yellow), and red, dimeric [(C6H11NC)8Rh(I)2]Cl2.0.5C6H6.2H2O have been crystallized.

Entities:  

Year:  2006        PMID： 16514462     DOI： 10.1039/b513700d

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Strong metal-metal Pauli repulsion leads to repulsive metallophilicity in closed-shell d8 and d10 organometallic complexes.

Authors:  Qingyun Wan; Jun Yang; Wai-Pong To; Chi-Ming Che
Journal:  Proc Natl Acad Sci U S A       Date:  2021-01-05       Impact factor: 11.205
  1 in total

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