Thermochemistry of the activation of N2 on iron cluster cations: Guided ion beam studies of the reactions of Fe(n)+ (n = 1-19) with N2.

The kinetic energy dependences of the reactions of Fe(n)+ (n = 1-19) with N2 are studied in a guided ion beam tandem mass spectrometer over the energy range of 0-15 eV. In addition to collision-induced dissociation forming Fe(m)+ ions, which dominate the product spectra, a variety of Fe(m)N2+ and Fe(m)N+ product ions, where m < or = n, is observed. All processes are observed to exhibit thresholds. Fe(m)+ - N and Fe(m)+ - 2N bond energies as a function of cluster size are derived from the threshold analysis of the kinetic energy dependences of the endothermic reactions. The trends in this thermochemistry are compared to the isoelectronic D0(Fe(n)+ - CH), and to bulk phase values. A fairly uniform barrier of 0.48+/-0.03 eV at 0 K is observed for formation of the Fe(n)N2+ product ions (n = 12, 15-19) and can be related to the rate-limiting step in the Haber process for catalytic ammonia production.