Literature DB >> 16505916

The oxidation of organocuprates--an offbeat strategy for synthesis.

David S Surry1, David R Spring.   

Abstract

The creation of carbon-carbon and carbon-heteroatom bonds by the oxidation of organocuprates is useful in a range of challenging contexts including the formation of biaryl bonds within medium rings, diene synthesis and the coupling of tertiary carbon centres. This tutorial review introduces these applications and recent developments which have served to improve its functional group tolerance and its utility in organic synthesis.

Entities:  

Year:  2005        PMID: 16505916     DOI: 10.1039/b508391p

Source DB:  PubMed          Journal:  Chem Soc Rev        ISSN: 0306-0012            Impact factor:   54.564


  6 in total

1.  Assignment and stereocontrol of hibarimicin atropoisomers.

Authors:  Ian M Romaine; Jonathan E Hempel; Ganesh Shanmugam; Hiroshi Hori; Yasuhiro Igarashi; Prasad L Polavarapu; Gary A Sulikowski
Journal:  Org Lett       Date:  2011-08-03       Impact factor: 6.005

2.  Total syntheses of secalonic acids A and D.

Authors:  Tian Qin; John A Porco
Journal:  Angew Chem Int Ed Engl       Date:  2014-02-12       Impact factor: 15.336

3.  Studies on a biomimetic oxidative dimerization approach to the hibarimicins.

Authors:  Ian M Romaine; Gary A Sulikowski
Journal:  Tetrahedron Lett       Date:  2015-06-03       Impact factor: 2.415

4.  Unravelling the hidden link of lithium halides and application in the synthesis of organocuprates.

Authors:  Hong Yi; Dali Yang; Jie Xin; Xiaotian Qi; Yu Lan; Yi Deng; Chih-Wen Pao; Jyh-Fu Lee; Aiwen Lei
Journal:  Nat Commun       Date:  2017-03-16       Impact factor: 14.919

5.  Diastereo- and enantioselective preparation of cyclopropanol derivatives.

Authors:  Marwan Simaan; Ilan Marek
Journal:  Beilstein J Org Chem       Date:  2019-03-21       Impact factor: 2.883

6.  Copper-Catalyzed Oxidative Cross-Coupling of Electron-Deficient Polyfluorophenylboronate Esters with Terminal Alkynes.

Authors:  Zhiqiang Liu; Yudha P Budiman; Ya-Ming Tian; Alexandra Friedrich; Mingming Huang; Stephen A Westcott; Udo Radius; Todd B Marder
Journal:  Chemistry       Date:  2020-11-09       Impact factor: 5.236

  6 in total

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