Literature DB >> 16491189

A non-fluorous copper catalyst for the styrene cyclopropanation reaction in a fluorous medium.

Juan Urbano1, Rocio Izarra, Jose Luis Gómez-Ariza, Swiatoslaw Trofimenko, M Mar Díaz-Requejo, Pedro J Pérez.   

Abstract

The complex Tp(Br3)Cu(NCMe) (1), containing no fluorine atoms, can be dissolved in the perfluoropolyether FOMBLIN and employed as a catalyst for the styrene cyclopropanation reaction with ethyl diazoacetate, with activities and diastereo-selectivities identical to those observed under homogeneous conditions with the advantage of being able to use a fluorous separation technique for catalyst recycling.

Entities:  

Year:  2006        PMID: 16491189     DOI: 10.1039/b517337j

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Catalytic synthesis of amino acid and peptide derivatized gadonanotubes.

Authors:  Yuri Mackeyev; Keith B Hartman; Jeyarama S Ananta; Adrian V Lee; Lon J Wilson
Journal:  J Am Chem Soc       Date:  2009-06-24       Impact factor: 15.419

  1 in total

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