| Literature DB >> 16489732 |
Abstract
We discuss several semiclassical Gaussian wave packet approaches with emphasis on one that is not very well-known, that is, the off-center guiding approach. Off-center guiding of (thawed) Gaussian wave packets uses the same information as other Gaussian propagation schemes, that is, the full van Vleck determinant and multiple trajectories. It retains the well-known caustic smoothing property of Gaussians. The off-center guiding of Gaussians can handle hard chaos and other highly nonlinear situations, where the van Vleck propagator, for example, has over 30,000 separate branches.Entities:
Year: 2006 PMID: 16489732 DOI: 10.1021/ar040196y
Source DB: PubMed Journal: Acc Chem Res ISSN: 0001-4842 Impact factor: 22.384