Literature DB >> 16486779

Onsager-Manning-Oosawa condensation phenomenon and the effect of salt.

Emmanuel Trizac1, Gabriel Téllez.   

Abstract

Making use of results pertaining to Painlevé III type equations, we revisit the celebrated Onsager-Manning-Oosawa condensation phenomenon for charged stiff linear polymers, in the mean-field approximation with salt. We obtain analytically the associated critical line charge density and show that it is severely affected by finite salt effects, whereas previous results focused on the no salt limit. In addition, we obtain explicit expressions for the condensate thickness and the electric potential. The case of asymmetric electrolytes is also briefly addressed.

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Year:  2006        PMID: 16486779     DOI: 10.1103/PhysRevLett.96.038302

Source DB:  PubMed          Journal:  Phys Rev Lett        ISSN: 0031-9007            Impact factor:   9.161


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