Literature DB >> 16478141

Paramagnetic active site models for the molybdenum-copper carbon monoxide dehydrogenase.

Craig Gourlay1, David J Nielsen, Jonathan M White, Sushilla Z Knottenbelt, Martin L Kirk, Charles G Young.   

Abstract

New paramagnetic, heterobimetallic Mo/Cu complexes featuring the Mo(=O)(mu-S)Cu core of O. carboxidovorans carbon monoxide dehydrogenase have been synthesized and structurally and spectroscopically characterized. The complexes exhibit EPR spectra (left graphic) indicative of extensive electron delocalization across the Mo-S-Cu core, in agreement with computational studies identifying the singly-occupied molecular orbital (right graphic).

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Year:  2006        PMID： 16478141     DOI： 10.1021/ja056500f

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  16 in total

Review 1.  Frontiers, opportunities, and challenges in biochemical and chemical catalysis of CO2 fixation.

Authors:  Aaron M Appel; John E Bercaw; Andrew B Bocarsly; Holger Dobbek; Daniel L DuBois; Michel Dupuis; James G Ferry; Etsuko Fujita; Russ Hille; Paul J A Kenis; Cheryl A Kerfeld; Robert H Morris; Charles H F Peden; Archie R Portis; Stephen W Ragsdale; Thomas B Rauchfuss; Joost N H Reek; Lance C Seefeldt; Rudolf K Thauer; Grover L Waldrop
Journal:  Chem Rev       Date:  2013-06-14       Impact factor: 60.622

2.  Kinetic and spectroscopic studies of the molybdenum-copper CO dehydrogenase from Oligotropha carboxidovorans.

Authors:  Bo Zhang; Craig F Hemann; Russ Hille
Journal:  J Biol Chem       Date:  2010-02-23       Impact factor: 5.157

Review 3.  The aerobic CO dehydrogenase from Oligotropha carboxidovorans.

Authors:  Russ Hille; Stephanie Dingwall; Jarett Wilcoxen
Journal:  J Biol Inorg Chem       Date:  2014-08-26       Impact factor: 3.358

Review 4.  The mononuclear molybdenum enzymes.

Authors:  Russ Hille; James Hall; Partha Basu
Journal:  Chem Rev       Date:  2014-01-28       Impact factor: 60.622

Review 5.  Electronic structure contributions to reactivity in xanthine oxidase family enzymes.

Authors:  Benjamin W Stein; Martin L Kirk
Journal:  J Biol Inorg Chem       Date:  2014-11-26       Impact factor: 3.358

6.  Orbital contributions to CO oxidation in Mo-Cu carbon monoxide dehydrogenase.

Authors:  Benjamin W Stein; Martin L Kirk
Journal:  Chem Commun (Camb)       Date:  2014-02-04       Impact factor: 6.222

7.  Biomimetic chemistry of iron, nickel, molybdenum, and tungsten in sulfur-ligated protein sites.

Authors:  Stanislav Groysman; R H Holm
Journal:  Biochemistry       Date:  2009-03-24       Impact factor: 3.162

8.  (13)C and (63,65)Cu ENDOR studies of CO dehydrogenase from Oligotropha carboxidovorans. Experimental evidence in support of a copper-carbonyl intermediate.

Authors:  Muralidharan Shanmugam; Jarett Wilcoxen; Diana Habel-Rodriguez; George E Cutsail; Martin L Kirk; Brian M Hoffman; Russ Hille
Journal:  J Am Chem Soc       Date:  2013-11-19       Impact factor: 15.419

9.  The hydrogenase activity of the molybdenum/copper-containing carbon monoxide dehydrogenase of Oligotropha carboxidovorans.

Authors:  Jarett Wilcoxen; Russ Hille
Journal:  J Biol Chem       Date:  2013-10-28       Impact factor: 5.157

10.  A realistic in silico model for structure/function studies of molybdenum-copper CO dehydrogenase.

Authors:  Dalia Rokhsana; Tao A G Large; Morgan C Dienst; Marius Retegan; Frank Neese
Journal:  J Biol Inorg Chem       Date:  2016-05-26       Impact factor: 3.358
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