Literature DB >> 16468828

Efficient and green telescoped process to 2-methoxy-3-methyl-[1,4]benzoquinone.

Raquel Rodríguez González1, Cristian Gambarotti, Lucia Liguori, Hans-René Bjørsvik.   

Abstract

A telescoped process for the preparation of 2-methoxy-3-methyl-[1,4]benzoquinone is disclosed. When this novel process is compared to the prevailing method that utilizes Na2Cr2O7 as the oxidant, the novel process represents a high yielding (95%), green, and environmentally benign alternative with H2O2 and HNO3 as the oxidants and CH3COOH as the reaction medium.

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Year:  2006        PMID: 16468828     DOI: 10.1021/jo0522512

Source DB:  PubMed          Journal:  J Org Chem        ISSN: 0022-3263            Impact factor:   4.354


  2 in total

1.  Composition of the defensive secretion in three species of European millipedes.

Authors:  Ljubodrag V Vujisić; Slobodan E Makarov; Božidar P M Curčić; Bojan S Ilić; Vele V Tešević; Dejan M Gođevac; Ivan M Vučković; Srećko B Curčić; Bojan M Mitić
Journal:  J Chem Ecol       Date:  2011-11-19       Impact factor: 2.626

2.  Oxidation of organotrifluoroborates via oxone.

Authors:  Gary A Molander; Livia N Cavalcanti
Journal:  J Org Chem       Date:  2010-12-30       Impact factor: 4.354

  2 in total

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