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Literature DB >> 16468754

An iron-containing ionic liquid as recyclable catalyst for aryl grignard cross-coupling of alkyl halides.

Abstract

[reaction: see text] The ionic liquid butylmethylimidazolium tetrachloroferrate (bmim-FeCl(4)) was found to be a very effective and completely air stable catalyst for the biphasic Grignard cross-coupling with primary and secondary alkyl halides bearing beta-hydrogens. After simply decanting the product in the ethereal layer, the ionic liquid catalyst was successfully recycled four times.

Entities: Chemical

Year: 2006 PMID： 16468754 DOI： 10.1021/ol052965z

Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005

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Cited

13 in total

1. Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.

Authors: Deidre L Sandrock; Ludivine Jean-Gérard; Cheng-yi Chen; Spencer D Dreher; Gary A Molander
Journal: J Am Chem Soc Date: 2010-11-15 Impact factor: 15.419

2. Combined Effects of Backbone and N-Substituents on Structure, Bonding, and Reactivity of Alkylated Iron(II)-NHCs.

Authors: Salvador B Muñoz; Valerie E Fleischauer; William W Brennessel; Michael L Neidig
Journal: Organometallics Date: 2018-09-06 Impact factor: 3.876

3. Visible-light-induced cross-coupling of aryl iodides with hydrazones via an EDA-complex.

Authors: Pan Pan; Shihan Liu; Yu Lan; Huiying Zeng; Chao-Jun Li
Journal: Chem Sci Date: 2022-05-23 Impact factor: 9.969

4. Efficient cross-coupling of secondary alkyltrifluoroborates with aryl chlorides--reaction discovery using parallel microscale experimentation.

Authors: Spencer D Dreher; Peter G Dormer; Deidre L Sandrock; Gary A Molander
Journal: J Am Chem Soc Date: 2008-06-27 Impact factor: 15.419

9. Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties.

Authors: Kerstin Zehbe; Matthias Kollosche; Sebastian Lardong; Alexandra Kelling; Uwe Schilde; Andreas Taubert
Journal: Int J Mol Sci Date: 2016-03-16 Impact factor: 5.923

10. Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction.

Authors: Maren Muntzeck; René Wilhelm
Journal: Int J Mol Sci Date: 2016-06-01 Impact factor: 5.923

An iron-containing ionic liquid as recyclable catalyst for aryl grignard cross-coupling of alkyl halides.

1. Stereospecific cross-coupling of secondary alkyl β-trifluoroboratoamides.

2. Combined Effects of Backbone and N-Substituents on Structure, Bonding, and Reactivity of Alkylated Iron(II)-NHCs.

3. Visible-light-induced cross-coupling of aryl iodides with hydrazones via an EDA-complex.

4. Efficient cross-coupling of secondary alkyltrifluoroborates with aryl chlorides--reaction discovery using parallel microscale experimentation.

5. Oxidative Addition of Aryl and Alkyl Halides to a Reduced Iron Pincer Complex.

6. Tetrachloridocuprates(II)-synthesis and electron paramagnetic resonance (EPR) spectroscopy.

7. Total Synthesis of (±)-Paroxetine by Diastereoconvergent Cobalt-Catalysed Arylation.

8. Tetrabromidocuprates(II)-Synthesis, Structure and EPR.

9. Ionogels Based on Poly(methyl methacrylate) and Metal-Containing Ionic Liquids: Correlation between Structure and Mechanical and Electrical Properties.

10. Influence of Ionic Liquids on an Iron(III) Catalyzed Three-Component Coupling/Hydroarylation/Dehydrogenation Tandem Reaction.