Literature DB >> 16465326

A paramagnetic Cu(I)/Cu(II)/Zn(II) coordination polymer with multiple CN-binding modes and its solid-state NMR characterization.

Liang Ouyang1, Pedro M Aguiar, Raymond J Batchelor, Scott Kroeker, Daniel B Leznoff.   

Abstract

A Cu(I)/Cu(II)/Zn(II) mixed-valent [Cu(en)2][Zn(NC)4(CuCN)2] polymer, which has a 2-D layer structure with six structurally inequivalent cyanides in four distinct bonding modes, has been prepared; structurally informative 13C and 15N MAS NMR spectra of this paramagnetic system are readily observable.

Entities:  

Year:  2006        PMID: 16465326     DOI: 10.1039/b512430a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  1 in total

1.  Distinguishing polymorphs of the semiconducting pigment copper phthalocyanine by solid-state NMR and Raman spectroscopy.

Authors:  Medhat A Shaibat; Leah B Casabianca; Diana Y Siberio-Pérez; Adam J Matzger; Yoshitaka Ishii
Journal:  J Phys Chem B       Date:  2010-04-08       Impact factor: 2.991

  1 in total

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