Literature DB >> 16456291

An oximino tautomer of 1-n-decyl-4-hydroxyimino-3-methyl-1H-pyrazol-5(4H)-one.

Julio Belmar1, Claudio Jiménez, Leandro Ortiz, María Teresa Garland, Ricardo Baggio.   

Abstract

The title compound, C14H25N3O2, consists of a five-membered heterocyclic ring to which a pendant decyl group is attached. The oximino tautomeric character of the molecule is clearly defined by the distribution of well defined double bonds in the heterocycle region (one C=O and two C=N). The most conspicuous packing interaction is the strong intermolecular hydrogen bond linking the oximino OH group and the carbonyl O atom to define broad planar hydrophilic strips running along the unique b axis. The alkyl chains adopt a fully extended conformation and lie almost at right angles to these one-dimensional structures, defining their hydrophobic counterpart.

Entities:  

Year:  2006        PMID: 16456291     DOI: 10.1107/S0108270105042204

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  2 in total

1.  2-Phenyl-5-(trifluoro-meth-yl)pyrazol-3(2H)-one.

Authors:  Hugo Gallardo; Edivandro Girotto; Adailton J Bortoluzzi; Geovana G Terra
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-07-29

2.  1-(5-Hydroxy-1-phenyl-3-trifluoromethyl-1H-pyrazol-1-yl)ethanone.

Authors:  Hugo Gallardo; Edivandro Girotto; Adailton J Bortoluzzi
Journal:  Acta Crystallogr Sect E Struct Rep Online       Date:  2009-12-09
  2 in total

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