Literature DB >> 16448082

Synthesis and structural characterization of endohedral pyrrolidinodimetallofullerene: La2@C80(CH2)2NTrt.

Michio Yamada1, Takatsugu Wakahara, Tsukasa Nakahodo, Takahiro Tsuchiya, Yutaka Maeda, Takeshi Akasaka, Kenji Yoza, Ernst Horn, Naomi Mizorogi, Shigeru Nagase.   

Abstract

The endohedral pyrrolidinodimetallofullerene, La2@C80(CH2)2NTrt (Trt = triphenylmethyl), was successfully synthesized and characterized. X-ray crystallographic and NMR spectroscopic analyses reveal that two La atoms in the 6,6-adduct are localized at the stable site on the mirror plane. Theoretical calculation also suggests the localization of two La atoms in the 6,6-adduct.

Entities:  

Year:  2006        PMID： 16448082     DOI： 10.1021/ja056560l

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  4 in total

1.  Biomedical activities of endohedral metallofullerene optimized for nanopharmaceutics.

Authors:  Jie Meng; Dong-liang Wang; Paul C Wang; Lee Jia; Chunying Chen; Xing-Jie Liang
Journal:  J Nanosci Nanotechnol       Date:  2010-12

2.  The dynamic motion of a M (M = Ca, Yb) atom inside the C₇₄ (D₃h) cage: a relativistic DFT study.

Authors:  Wei Zheng; Suzhen Ren; Dongxu Tian; Ce Hao
Journal:  J Mol Model       Date:  2013-08-14       Impact factor: 1.810

Review 3.  Functionalization of Endohedral Metallofullerenes with Reactive Silicon and Germanium Compounds.

Authors:  Masahiro Kako; Shigeru Nagase; Takeshi Akasaka
Journal:  Molecules       Date:  2017-07-14       Impact factor: 4.411

4.  Thermodynamically stable [4 + 2] cycloadducts of lanthanum-encapsulated endohedral metallofullerenes.

Authors:  Yuta Takano; Yuki Nagashima; M Ángeles Herranz; Nazario Martín; Takeshi Akasaka
Journal:  Beilstein J Org Chem       Date:  2014-03-25       Impact factor: 2.883
  4 in total

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