Literature DB >> 16448081

Analysis of lanthanide-induced NMR shifts of the Ce@C82 anion.

Michio Yamada1, Takatsugu Wakahara, Yongfu Lian, Takahiro Tsuchiya, Takeshi Akasaka, Markus Waelchli, Naomi Mizorogi, Shigeru Nagase, Karl M Kadish.   

Abstract

The mapping of bond connectivity in the carbon cage of [Ce@C82]- and full assignment of the NMR lines were successfully achieved by means of 2D INADEQUATE NMR measurement. Paramagnetic NMR analysis shows that the Ce atom in [Ce@C82]- is located at an off-centered position adjacent to a hexagonal ring along the C2 axis of the C2v-C82 cage.

Entities:  

Year:  2006        PMID： 16448081     DOI： 10.1021/ja055882m

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Magnetic anisotropy of endohedral lanthanide ions: paramagnetic NMR study of MSc2N@C80-Ih with M running through the whole 4f row.

Authors:  Y Zhang; D Krylov; M Rosenkranz; S Schiemenz; A A Popov
Journal:  Chem Sci       Date:  2015-01-28       Impact factor: 9.825

2.  Confining the spin between two metal atoms within the carbon cage: redox-active metal-metal bonds in dimetallofullerenes and their stable cation radicals.

Authors:  Nataliya A Samoylova; Stanislav M Avdoshenko; Denis S Krylov; Hannah R Thompson; Amelia C Kirkhorn; Marco Rosenkranz; Sandra Schiemenz; Frank Ziegs; Anja U B Wolter; Shangfeng Yang; Steven Stevenson; Alexey A Popov
Journal:  Nanoscale       Date:  2017-06-14       Impact factor: 7.790
  2 in total

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