Literature DB >> 16446829

A molecular pinwheel multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ with mu4-sulfido, mu3-thiolato and nitrogen ligands.

Yunho Lee1, Amy A Narducci Sarjeant, Kenneth D Karlin.   

Abstract

A copper(I) complex with new N2S thiol ligand transforms to a multicopper(I) cluster, [(L(S-))6Cu(I)13(S2-)2]3+ (1); its X-ray structure exhibiting mu4-sulfido and mu3-thiolato coordination is presented and compared to other cuprous thiolato/sulfido clusters including that observed in the copper enzyme nitrous oxide reductase.

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Year:  2005        PMID： 16446829     DOI： 10.1039/b513768c

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  4 in total

1.  Ligand structural effects on Cu2S2 bonding and reactivity in side-on disulfido-bridged dicopper complexes.

Authors:  Eric C Brown; Itsik Bar-Nahum; John T York; Nermeen W Aboelella; William B Tolman
Journal:  Inorg Chem       Date:  2007-01-22       Impact factor: 5.165

2.  Copper-Sulfur Complexes Supported by N-Donor Ligands: Towards Models of the Cu(Z) Site in Nitrous Oxide Reductase.

Authors:  John T York; Itsik Bar-Nahum; William B Tolman
Journal:  Inorganica Chim Acta       Date:  2008-03-03       Impact factor: 2.545

3.  Synthesis, structure, and reactions of a copper-sulfido cluster comprised of the parent Cu2S unit: {(NHC)Cu}2(μ-S).

Authors:  Junjie Zhai; Alexander S Filatov; Gregory L Hillhouse; Michael D Hopkins
Journal:  Chem Sci       Date:  2015-10-20       Impact factor: 9.825

4.  Linked supramolecular building blocks for enhanced cluster formation.

Authors:  Ross McLellan; Maria A Palacios; Christine M Beavers; Simon J Teat; Stergios Piligkos; Euan K Brechin; Scott J Dalgarno
Journal:  Chemistry       Date:  2015-01-09       Impact factor: 5.236
  4 in total

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