| Literature DB >> 16435842 |
Shenghai Li1, Yingjie Lin, Haibo Xie, Suobo Zhang, Jianing Xu.
Abstract
[reaction: see text]. Brønsted acid-base ionic liquids (GILs) based on guanidine and acetic acid are efficient reaction media for palladium-catalyzed Heck reactions. They offer the advantages of high activity and reusability. GIL2 plays multiple roles in the reaction: it could act as solvent, as a strong base to facilitate beta-hydride elimination, and as a ligand to stabilize activated Pd species.Entities:
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Year: 2006 PMID： 16435842 DOI： 10.1021/ol052543p
Source DB: PubMed Journal: Org Lett ISSN： 1523-7052 Impact factor: 6.005