Literature DB >> 16433507

Synthesis of tetrasubstituted and functionalized enol ethers by E-selective olefination of esters with ynolates.

Mitsuru Shindo1, Taisuke Kita, Toshihiro Kumagai, Kenji Matsumoto, Kozo Shishido.   

Abstract

We have developed the E-selective olefination of ester carbonyls to afford tetrasubstituted, functionalized olefins and the C-S insertion of thiol esters to give beta-keto thiol esters via ynolates.

Entities:  

Year:  2006        PMID： 16433507     DOI： 10.1021/ja0561082

Source DB:  PubMed          Journal:  J Am Chem Soc        ISSN： 0002-7863            Impact factor:   15.419


  2 in total

1.  Functionalized α,α-dibromo esters through Claisen rearrangements of dibromoketene acetals.

Authors:  Nathan J Dupper; Ohyun Kwon
Journal:  Org Lett       Date:  2015-02-11       Impact factor: 6.005

2.  Silver-Catalyzed Aldehyde Olefination Using Siloxy Alkynes.

Authors:  Jianwei Sun; Valerie A Keller; S Todd Meyer; Sergey A Kozmin
Journal:  Adv Synth Catal       Date:  2010-03-20       Impact factor: 5.837
  2 in total

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