| Literature DB >> 16417345 |
Alexei A Belik1, Satoshi Iikubo, Katsuaki Kodama, Naoki Igawa, Shin-ichi Shamoto, Makoto Maie, Takuro Nagai, Yoshio Matsui, Sergey Yu Stefanovich, Bogdan I Lazoryak, Eiji Takayama-Muromachi.
Abstract
With neutron powder diffraction, electron diffraction, and second-harmonic generation, we have shown that BiScO3 has a structure closely related to that of multiferroic BiMnO3, but BiScO3 crystallizes in the centrosymmetric space group of C2/c. These results bring up a question about the origin of ferroelectricity in BiMnO3. BiScO3 may serve as a model system to understand the role of Mn3+ ions in the ferroelectricity of BiMnO3.Entities:
Year: 2006 PMID: 16417345 DOI: 10.1021/ja057574u
Source DB: PubMed Journal: J Am Chem Soc ISSN: 0002-7863 Impact factor: 15.419