Literature DB >> 16414065

Calculation of hydrophile-lipophile balance for polyethoxylated surfactants by group contribution method.

Xiaowen Guo1, Zongming Rong, Xugen Ying.   

Abstract

Based on Davies' group contribution method, hydrophile-lipophile balance (HLB) values were calculated by effective chain length (ECL) instead of actual chain length of straight alkyl chain, polyoxyethylene (EO) chain, and polyoxypropylene (PO) chain. Linear equations were adopted for the effective chain length of straight alkyl chain and PO chain; a Gamma probability density function (PDF) was used to describe the contribution of each EO group to HLB and the effective chain length of EO chain could be obtained by integrating Gamma PDF. The HLB values of 224 nonionic surfactants were calculated and the average absolute error is less than 1.5, which is much better than the results obtained by Davies.

Entities:  

Year:  2006        PMID： 16414065     DOI： 10.1016/j.jcis.2005.12.009

Source DB:  PubMed          Journal:  J Colloid Interface Sci        ISSN： 0021-9797            Impact factor:   8.128


  6 in total

1.  Hydrophilic and lipophilic characteristics of non-fatty acid moieties: significant factors affecting antibacterial activity of lauric acid esters.

Authors:  Kyung-Min Park; Seon Joo Lee; Hyunjong Yu; Jun-Young Park; Ho-Sup Jung; Keesung Kim; Chang Joo Lee; Pahn-Shick Chang
Journal:  Food Sci Biotechnol       Date:  2018-03-15       Impact factor: 2.391

2.  Selective Synthesis of Polyoxyethylene-Polyoxypropylene Block Copolymer (Poloxamer) Fatty Acid Monoesters Over Homogeneous Organotin Catalyst.

Authors:  Janusz Nowicki; Julia Woch; Małgorzata Mościpan; Andrzej Robaszkiewicz; Rafał Grabowski; Izabela Semeniuk; Karol Erfurt
Journal:  J Surfactants Deterg       Date:  2017-09-26       Impact factor: 1.902

3.  Erythromycin Modification That Improves Its Acidic Stability while Optimizing It for Local Drug Delivery.

Authors:  Erika L Cyphert; Jaqueline D Wallat; Jonathan K Pokorski; Horst A von Recum
Journal:  Antibiotics (Basel)       Date:  2017-04-25

Review 4.  Gemini and Bicephalous Surfactants: A Review on Their Synthesis, Micelle Formation, and Uses.

Authors:  Lluvia Guerrero-Hernández; Héctor Iván Meléndez-Ortiz; Gladis Y Cortez-Mazatan; Sandra Vaillant-Sánchez; René D Peralta-Rodríguez
Journal:  Int J Mol Sci       Date:  2022-02-04       Impact factor: 5.923

5.  Evaluation of the leather fatliquoring potential of sulphonated Afzelia africana aril cap oil.

Authors:  Adachukwu N Nkwor; Pius O Ukoha
Journal:  Heliyon       Date:  2019-12-27

6.  Synthesis, Characterization, and Evaluation of Solution Properties of Sesame Fatty Methyl Ester Sulfonate Surfactant.

Authors:  Soy R C; Pius K Kipkemboi; Kiplangat Rop
Journal:  ACS Omega       Date:  2020-10-30
  6 in total

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