Literature DB >> 16411717

Quantum chemistry predicts multiply bonded diuranium compounds to be stable.

Björn O Roos1, Laura Gagliardi.   

Abstract

Results from quantum chemical calculations that predict the existence of a series of diuranium molecules are reported. Two diuranium chlorides, U(2)Cl(6) and U(2)Cl(8)(2)(-), and three different carboxylates, U(2)(OCHO)(4), U(2)(OCHO)(6), and U(2)(OCHO)(4)Cl(2) have been studied. All species have been found to be stable with a multiply bonded U(2) unit.

Entities:  

Year:  2006        PMID： 16411717     DOI： 10.1021/ic051665a

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  4 in total

1.  Identification of a uranium-rhodium triple bond in a heterometallic cluster.

Authors:  Genfeng Feng; Mingxing Zhang; Penglong Wang; Shuao Wang; Laurent Maron; Congqing Zhu
Journal:  Proc Natl Acad Sci U S A       Date:  2019-08-19       Impact factor: 11.205

2.  A crystalline tri-thorium cluster with σ-aromatic metal-metal bonding.

Authors:  Josef T Boronski; John A Seed; David Hunger; Adam W Woodward; Joris van Slageren; Ashley J Wooles; Louise S Natrajan; Nikolas Kaltsoyannis; Stephen T Liddle
Journal:  Nature       Date:  2021-08-23       Impact factor: 49.962

3.  A Very Short Uranium(IV)-Rhodium(I) Bond with Net Double-Dative Bonding Character.

Authors:  Erli Lu; Ashley J Wooles; Matthew Gregson; Philip J Cobb; Stephen T Liddle
Journal:  Angew Chem Int Ed Engl       Date:  2018-04-27       Impact factor: 15.336

4.  Construction of heterometallic clusters with multiple uranium-metal bonds by using dianionic nitrogen-phosphorus ligands.

Authors:  Genfeng Feng; Karl N McCabe; Shuao Wang; Laurent Maron; Congqing Zhu
Journal:  Chem Sci       Date:  2020-03-13       Impact factor: 9.825
  4 in total

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