Literature DB >> 16411682

Novel phosphoranido complex of rhodium(III) tetraphenylporphyrin. Synthesis and characterization.

Kazumasa Kajiyama1, Takeshi K Miyamoto, Kaita Sawano.   

Abstract

A novel phosphoranido complex of rhodium(III) porphyrin was prepared by the reaction of a lithium phosphoranide, generated from a P-H phosphorane bearing two 8-oxy-1-naphthyl groups, with (TPP)RhCl (TPP = dianion of 5,10,15,20-tetraphenylporphyrin). The crystal structure of the complex was determined by X-ray structural analysis.

Entities:  

Year:  2006        PMID: 16411682     DOI: 10.1021/ic051655+

Source DB:  PubMed          Journal:  Inorg Chem        ISSN: 0020-1669            Impact factor:   5.165


  1 in total

1.  Insertion of a Nontrigonal Phosphorus Ligand into a Transition Metal-Hydride: Direct Access to a Metallohydrophosphorane.

Authors:  Akira Tanushi; Alexander T Radosevich
Journal:  J Am Chem Soc       Date:  2018-06-25       Impact factor: 15.419

  1 in total

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