Literature DB >> 16397335

Compounds of glycine with metal sulfates and thiosulfates: glycine cobalt sulfate pentahydrate, glycine sodium thiosulfate dihydrate and glycine potassium thiosulfate.

Michel Fleck1, Ladislav Bohatý.   

Abstract

In the crystal structures of the title compounds, hexaaquacobalt(II) tetraaquadiglycinatocobalt(II) bis(sulfate), [Co(H2O)6][Co(C2H5NO2)2(H2O)4](SO4)2, (I), poly[diaqua-mu3-glycinato-di-mu4-thiosulfato-tetrasodium(I)], [Na4(C2H5NO2)(S2O3)2(H2O)2]n, (II), and poly[mu2-glycinato-mu4-thiosulfato-dipotassium(I)], [K2(C2H5NO2)(S2O3)]n, (III), all atoms are located on general positions, except the Co atoms in (I), which are located on inversion centres. In (I), hydrogen bonds play an important role, while the alkali thiosulfate compounds are characterized by three-dimensional frameworks of polyhedra. Relations to other compounds of glycine and metal sulfates are commented on.

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Year:  2005        PMID: 16397335     DOI: 10.1107/S0108270105040606

Source DB:  PubMed          Journal:  Acta Crystallogr C        ISSN: 0108-2701            Impact factor:   1.172


  1 in total

1.  Glycine zinc sulfate penta-hydrate: redetermination at 10 K from time-of-flight neutron Laue diffraction.

Authors:  A Dominic Fortes; Christopher M Howard; Ian G Wood; Matthias J Gutmann
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2016-09-16
  1 in total

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