Literature DB >> 16391744

Silylzincation of carbon-carbon multiple bonds revisited.

Gertrud Auer1, Martin Oestreich.   

Abstract

The first investigation of the copper-catalyzed silylzincation of alkynes as well as a diene and styrene using bis(triorganosilyl) zinc reagents led to the development of an efficient procedure and the disclosure of an unexpected bissilylation and unforeseen regioselectivity.

Entities:  

Year:  2005        PMID: 16391744     DOI: 10.1039/b513528a

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN: 1359-7345            Impact factor:   6.222


  2 in total

1.  Direct synthesis and applications of solid silylzinc reagents.

Authors:  Revathi Chandrasekaran; Feba Thomas Pulikkottil; Krishna Suresh Elama; Ramesh Rasappan
Journal:  Chem Sci       Date:  2021-11-30       Impact factor: 9.825

2.  Sodium silylsilanolate as a precursor of silylcopper species.

Authors:  Hiroki Yamagishi; Kenshiro Hitoshio; Jun Shimokawa; Hideki Yorimitsu
Journal:  Chem Sci       Date:  2022-03-21       Impact factor: 9.825

  2 in total

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