| Literature DB >> 16372086 |
Sune Nygaard1, Bo W Laursen, Amar H Flood, Camilla N Hansen, Jan O Jeppesen, J Fraser Stoddart.
Abstract
A highly constrained [2]rotaxane, constructed in such a way that the tetracationic cyclobis(paraquat-p-phenylene) ring is restricted to reside on a monopyrrolotetrathiafulvalene unit, has been synthesised and characterised. This design allows the deslipping free energy barrier for the tetracationic ring in all three redox states of the rotaxane to be determined.Entities:
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Year: 2005 PMID: 16372086 DOI: 10.1039/b511575b
Source DB: PubMed Journal: Chem Commun (Camb) ISSN: 1359-7345 Impact factor: 6.222