Literature DB >> 16363828

mer-[Fe(pcq)(CN)3]-: a novel cyanide-containing building block and its application to assembling cyanide-bridged trinuclear FeIII2MnII complexes [pcq- = 8-(pyridine-2-carboxamido)quinoline anion].

Zhong-Hai Ni1, Hui-Zhong Kou, Li-Fang Zhang, Wei-Wei Ni, Yun-Bo Jiang, Ai-Li Cui, Joan Ribas, Osamu Sato.   

Abstract

A new cyanide-containing building block K[Fe(pcq)(CN)(3)] [1; pcq(-) = 8-(pyridine-2-carboxamido)quinoline anion] containing a low-spin Fe(III) center with three cyanide groups in a meridional arrangement has been successfully designed and synthesized. Three cyanide-bridged trinuclear Fe(III)(2)Mn(II) complexes, [Fe(pcq)(CN)(3)](2)[Mn(CH(3)OH)(2)(H(2)O)(2)].2H(2)O (2), [Fe(pcq)(CN)(3)](2)[Mn(bipy)(2)].CH(3)OH.2H(2)O (3), and [Fe(pcq)(CN)(3)](2)[Mn(phen)(2)].CH(3)OH.2H(2)O (4), have been synthesized and structurally characterized. The magnetic susceptibilities of the three heterometallic complexes have been investigated.

Entities:  

Year:  2005        PMID： 16363828     DOI： 10.1021/ic051385v

Source DB:  PubMed          Journal:  Inorg Chem        ISSN： 0020-1669            Impact factor:   5.165


  2 in total

1.  The crystal structures of the ligand N-(quinolin-8-yl)pyrazine-2-carboxamide and of a tetra-nuclear copper(II) complex.

Authors:  Dilovan S Cati; Helen Stoeckli-Evans
Journal:  Acta Crystallogr E Crystallogr Commun       Date:  2019-05-10

2.  Various Structural Types of Cyanide-Bridged FeIII-MnIII Bimetallic Coordination Polymers (CPs) and Polynuclear Clusters Based-on A New mer-Tricyanoiron(III)Building Block: Synthesis, Crystal Structures, and Magnetic Properties.

Authors:  Wenlong Lan; Xiaoyun Hao; Yong Dou; Zhen Zhou; Lu Yang; Hui Liu; Dacheng Li; Yunhui Dong; Lingqian Kong; Daopeng Zhang
Journal:  Polymers (Basel)       Date:  2019-09-27       Impact factor: 4.329
  2 in total

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