Identification of wastewater sludge characteristics to predict critical flux for membrane bioreactor processes.

The effects of sludge characteristics on critical flux were examined using a submerged membrane bioreactor pilot plant operated under different process conditions to treat municipal wastewater. The sludge in the membrane tank was characterized by measuring colloidal particle concentration, extracellular polymeric substances (EPS), mixed liquor suspended solids (MLSS), temperature, time to filter (TTF) and diluted sludge volume index (DSVI). The colloidal particle concentration was represented by the colloidal total organic carbon (TOC), which is the TOC difference between the filtrate passing through a 1.5 microm pore size filter and the permeate collected from pilot ultrafiltration membrane modules with a pore size of 0.04 microm. The results showed that the critical flux measured by the stepwise flux method was almost solely related to the colloidal TOC despite different sludges tested. In contrast, MLSS was shown to have little impact on the critical flux within the range examined. Neither TTF nor DSVI could be used to reliably predict the critical flux. Furthermore, colloidal TOC can be attributed to soluble EPS, but not bound EPS. Therefore, it is suggested that colloidal TOC be used as a new filterability index for MBR processes in wastewater treatment.