Literature DB >> 16358058

Cross-metathesis of unsaturated natural oils with 2-butene. High conversion and productive catalyst turnovers.

Jim Patel1, Jomana Elaridi, W Roy Jackson, Andrea J Robinson, Algirdas K Serelis, Chris Such.   

Abstract

The cross-metathesis of synthetic and natural triglycerides containing unsaturated fatty acids with 2-butene can be achieved with high conversion and excellent productive turnovers. These reactions are catalysed by second-generation ruthenium-based olefin metathesis catalysts and can be conducted at -5 degrees C in liquid 2-butene.

Entities:  

Year:  2005        PMID： 16358058     DOI： 10.1039/b511626k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  5 in total

1.  Direct valorisation of waste cocoa butter triglycerides via catalytic epoxidation, ring-opening and polymerisation.

Authors:  Dorota D Plaza; Vinzent Strobel; Parminder Kaur Ks Heer; Andrew B Sellars; Seng-Soi Hoong; Andrew J Clark; Alexei A Lapkin
Journal:  J Chem Technol Biotechnol       Date:  2017-05-24       Impact factor: 3.174

2.  Functionalized ionic liquids based on vegetable oils for rare earth elements recovery.

Authors:  Fujian Li; Jingyao Zeng; Xiaoqi Sun
Journal:  RSC Adv       Date:  2020-07-16       Impact factor: 4.036

3.  Sunflower-based feedstocks in nonfood applications: Perspectives from olefin metathesis.

Authors:  Bassie B Marvey
Journal:  Int J Mol Sci       Date:  2008-08-13       Impact factor: 6.208

4.  Continuous Flow Metathesis for Direct Valorization of Food Waste: An Example of Cocoa Butter Triglyceride.

Authors:  Christiane Schotten; Dorota Plaza; Simone Manzini; Steven P Nolan; Steven V Ley; Duncan L Browne; Alexei Lapkin
Journal:  ACS Sustain Chem Eng       Date:  2015-05-26       Impact factor: 8.198

5.  Bis(Cyclic Alkyl Amino Carbene) Ruthenium Complexes: A Versatile, Highly Efficient Tool for Olefin Metathesis.

Authors:  Rafał Gawin; Anna Kozakiewicz; Piotr A Guńka; Paweł Dąbrowski; Krzysztof Skowerski
Journal:  Angew Chem Int Ed Engl       Date:  2016-12-12       Impact factor: 15.336
  5 in total

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