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Literature DB >> 16358050

A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2](12-): synthesis and structural characterisation of the bis-{Ru(p-cymene)}(2+)-containing anion [Sb2W20O70{Ru(p-cymene)}2](10-).

Danielle Laurencin¹, Richard Villanneau, Patrick Herson, René Thouvenot, Yves Jeannin, Anna Proust.

Abstract

The easy synthesis of [Sb2W20O70{Ru(p-cymene)}2](10-) by the reaction between the organometallic precursor [Ru(p-cymene)Cl2]2 and [Sb2W20O70]14-, formed in situ, confirms the importance of the organometallic route to well defined ruthenium(+II)-substituted heteropolytungstates.

Entities: Chemical

Year: 2005 PMID： 16358050 DOI： 10.1039/b510300b

Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222

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Cited

1 in total

1. Organorhodium(III)- and Iridium(III)-Substituted 20-Tungstobismuthates(III) and -Antimonates(III), [(MCp*)₂X₂W₂₀O₇₀]^10- (M = Rh^III and Ir^III; X = Bi^III and Sb^III).

Authors: Ali S Mougharbel; Sihana Ahmedi; Saurav Bhattacharya; Ananthu Rajan; Ulrich Kortz
Journal: ACS Omega Date: 2021-12-08

1 in total

A new organometallic heteropolytungstate related to [Sb2W22O74(OH)2](12-): synthesis and structural characterisation of the bis-{Ru(p-cymene)}(2+)-containing anion [Sb2W20O70{Ru(p-cymene)}2](10-).

1. Organorhodium(III)- and Iridium(III)-Substituted 20-Tungstobismuthates(III) and -Antimonates(III), [(MCp*)2X2W20O70]10- (M = RhIII and IrIII; X = BiIII and SbIII).

1. Organorhodium(III)- and Iridium(III)-Substituted 20-Tungstobismuthates(III) and -Antimonates(III), [(MCp*)₂X₂W₂₀O₇₀]^10- (M = Rh^III and Ir^III; X = Bi^III and Sb^III).