| Literature DB >> 16358047 |
Samadara Thushari1, John A K Cha, Herman H-Y Sung, Stephen S-Y Chui, Andy L-F Leung, Yu-Fong Yen, Ian D Williams.
Abstract
L-Tartrate ions can endure hydrothermal conditions up to 160 degrees C to form the robust, enantiopure open-framework coordination polymers [Ln2(L-TAR)3(H2O)2]3H2O, 1; the addition of succinate results in formation of the related [Ln2(L-TAR)2(SUC)(H2O)2]5.5H2O, with larger channels than , whereas racemic D/L-tartrate gives the more condensed [Ln2(D/L-TAR)3(H2O)2], . TAR = [C4H4O6]2-.Entities:
Year: 2005 PMID： 16358047 DOI： 10.1039/b508574h
Source DB: PubMed Journal: Chem Commun (Camb) ISSN： 1359-7345 Impact factor: 6.222