Literature DB >> 16357956

Synthesis of anionic methylpalladium complexes with phosphine-sulfonate ligands and their activities for olefin polymerization.

Takuya Kochi1, Kenji Yoshimura, Kyoko Nozaki.   

Abstract

Reaction of diarylphosphinobenzene-2-sulfonic acids with tertially amines, followed by addition of [PdMeCl(cod)], provided anionic methylpalladium(II) complexes with bidentate phosphine-sulfonate ligands, which show high activity for copolymerization of ethylene with methyl acrylate.

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Year:  2005        PMID： 16357956     DOI： 10.1039/b512452m

Source DB:  PubMed          Journal:  Dalton Trans        ISSN： 1477-9226            Impact factor:   4.390


  2 in total

1.  First microwave-assisted synthesis of an electron-rich phosphane and its coordination chemistry with platinum(II) and palladium(II)

Authors:  Barbara Trettenbrein; Markus Fessler; Martin Ruggenthaler; Stephan Haringer; Dennis Oberhuber; Georg Czermak; Peter Brüggeller; Werner Oberhauser
Journal:  Inorganica Chim Acta       Date:  2011-09-01       Impact factor: 2.545

2.  Ligand-controlled insertion regioselectivity accelerates copolymerisation of ethylene with methyl acrylate by cationic bisphosphine monoxide-palladium catalysts.

Authors:  Yusuke Mitsushige; Brad P Carrow; Shingo Ito; Kyoko Nozaki
Journal:  Chem Sci       Date:  2015-11-03       Impact factor: 9.825
  2 in total

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