Literature DB >> 16353100

Stabilisation of a paramagnetic BH(4-)-bridged dinickel(II) complex by a macrodinucleating hexaaza-dithiophenolate ligand.

Yves Journaux1, Vasile Lozan, Julia Klingele, Berthold Kersting.   

Abstract

The first paramagnetic borohydrido-bridged dinuclear nickel(II) complex, [(L)Ni(II)2(mu(1,3)-BH4)]+, stabilised by a sterically demanding hexaaza-dithiophenolate macrocycle, has been obtained by the reaction of [(L)Ni(II)2(micro-ClO4)]+ with N(n)Bu4BH4.

Entities:  

Year:  2005        PMID： 16353100     DOI： 10.1039/b512744k

Source DB:  PubMed          Journal:  Chem Commun (Camb)        ISSN： 1359-7345            Impact factor:   6.222


  1 in total

1.  Models for the hydrogenases put the focus where it should be--hydrogen.

Authors:  Carlo Mealli; Thomas B Rauchfuss
Journal:  Angew Chem Int Ed Engl       Date:  2007       Impact factor: 15.336
  1 in total

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