| Literature DB >> 16332061 |
Richard D Broene1, Maurice Brookhart, William M Lamanna, Anthony F Volpe.
Abstract
[Cp*P(OMe)3CoCH2CH3]+ [BarF]-, generated by the addition of HBArF to Cp*P(OMe)3Co(ethene), catalyzes the oligomerization of 1-hexene to give dimers and trimers. When a deficit of the acid is used, linear alpha-olefin dimers are produced at the expense of trimeric products: e.g., 1-butene, 1-hexene, and 1-octene give 1-octene, 1-dodecene, and 1-hexadecene, respectively.Entities:
Year: 2005 PMID： 16332061 DOI： 10.1021/ja056655n
Source DB: PubMed Journal: J Am Chem Soc ISSN： 0002-7863 Impact factor: 15.419