Literature DB >> 16331929

One-electron reduction of an "extended viologen" p-phenylene-bis-4,4'-(1-aryl-2,6-diphenylpyridinium) dication.

Alison Funston1, James P Kirby, John R Miller, Lubomír Pospísil, Jan Fiedler, Magdaléna Hromadová, Miroslav Gál, Jaroslav Pecka, Michal Valásek, Zbigniew Zawada, Pawel Rempala, Josef Michl.   

Abstract

One-electron reduction of the "extended viologen" dication 1 yields the red cation radical 2, characterized by strong near-IR absorption. It has been generated and studied by pulse radiolytic, electrochemical, redox titration, UV-visible, and electron paramagnetic resonance spectroscopic methods. All results are in agreement with a fully delocalized electronic structure for 2.

Entities:  

Year:  2005        PMID: 16331929     DOI: 10.1021/jp053556n

Source DB:  PubMed          Journal:  J Phys Chem A        ISSN: 1089-5639            Impact factor:   2.781


  2 in total

1.  Mechanically induced intramolecular electron transfer in a mixed-valence molecular shuttle.

Authors:  Jonathan C Barnes; Albert C Fahrenbach; Scott M Dyar; Marco Frasconi; Marc A Giesener; Zhixue Zhu; Zhichang Liu; Karel J Hartlieb; Ranaan Carmieli; Michael R Wasielewski; J Fraser Stoddart
Journal:  Proc Natl Acad Sci U S A       Date:  2012-06-08       Impact factor: 11.205

2.  Pyridinium-Functionalized Pyromellitic Diimides with Stabilized Radical Anion States.

Authors:  Andrew J Greenlee; Charles K Ofosu; Qifan Xiao; Mohammed M Modan; Daron E Janzen; Dennis D Cao
Journal:  ACS Omega       Date:  2018-01-09
  2 in total

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